第13章
The soda solution must not be poured into the gold, as the gold would be immediately decomposed, and the solution turn black, and be unfit for use.
Some operators add muriate of potash and other substances, but these do not possess any advantage except in cases where it is necessary to bleach the solarized portions of the impression, and when such is the case, chloride of sodium (common salt)is probably as effective and is the most convenient.
Add about a teaspoonful to two ounces of the gilding.
Solution, for Increasing the Brilliancy of the Daguerreotype.--This solution will have the effect to thoroughly cleanse the surface of the gilded plate and excite a powerful influence on the general character of the impression.
To a solution of three ounces of water, in which is dissolved a quarter of an ounce of cyanide of potassium, add one teaspoonful of a solution containing six ounces of water and half an ounce of each pure carbonate of potash, alum, common salt, gallic acid, sulphate of copper, and purified borax.
While the plate is wet, pour on a little, and heat it with a powerful blaze.
The effect will be quickly produced, in from three to fifteen seconds.
Rinse and dry, as in the gilding.
Bleaching Solution.--Make a saturated solution of muriate of ammonia (sal ammoniac) in pure water, and filter through paper.
Reduce with an equal quantity of water when used. When the linen or any other portion of the impression is badly solarized, after removing the coating, rinse with water; then pour this upon the surface in the same manner as the gilding solution.
If the solarization be very deep, apply the lamp beneath, and warm the plate a trifle. Now pour off, and, without rinsing, apply the gilding. The whole operation must be quickly performed, or the chlorine soon attacks the shades of the picture.
When properly done, however, the solarized parts are restored to a clear, transparent white.
Electro, or Cold Gilding.--This process I have adopted, and it produces exceedingly beautiful impressions for the stereoscope, adding a great charm to the pleasing effect of that instrument.
It also possesses a pretty and curious effect on views.
It is easy of trial, and may be used by dissolving one gramme of chloride of gold in half a litre of ordinary water, and thirty grammes of hyposulphite of soda in another half litre of similar water;then pour the solution of chloride of gold into that of soda, by little and little, agitating it exactly as in M. Fizeau's preparation, of which there is but a variation.
When you wish to use it, pour some into a plate, or any other vessel of the same kind, sufficient to cover the proof; then, after having added to it a drop of ammonia, immerse the plate in it as soon as you take it out of the mercury-box, after having wiped its back and edges, and agitate the mixture quickly from right to left, so as to dissolve rapidly the coating of iodide of silver as usual.
As soon as the plate appears white, cease all rapid motion, but continue to give it a slight undulating one; for if it were allowed to remain still for only a few minutes, the proof would be clouded.
By little and little, the surface of the plate takes a yellow tint, which darkens more and more, approaching to bistre. You stop therefore, at the color you wish; and when the proof has been washed and dried, in the manner previously explained, it will be found to be fixed, without any stain, with a limpid surface, and an extraordinary warm tone.
If you were to augment the proportions of the ammonia or chloride of gold, the operation would progress much quicker, but then the middle of the proof would be always much clearer than towards the border.
The mixture may be used several times without being renewed.
It does not, however, give such a beautiful color to the impression as when it is newly prepared. By communicating to the vessel containing the solution a continual motion, the impression, when once immersed, will be fixed. During that time, and while attending to anything else, watch its color; and at the end of ten minutes or a quarter of an hour, take it out of the bath and dry it.
Agent for Neutralizing Bromine, Chlorine, and Iodine Vapors.--Aqua ammonia, sprinkled about the chemical or coating room, will soon neutralize all the vapor in the atmosphere of either chlorine, bromine, or iodine. No operator should be without, at least, a six-ounce bottle filled with ammonia.
A little of its vapor about the camera-box has a decided and happy effect. Burnt coffee, pulverized, has also the property of destroying the vapors of the above chemicals, as also almost any other agent employed about the Daguerreotype room.
Its deodorizing properties are such that if brought in contact with air filled with the odor of decomposing meat, it will instantly destroy all disagreeable smell.
It can easily be used in the Daguerreotype room by placing a little of the raw bean, finely pulverized, on an old plate, and roasting it over the spirit-lamp.
Buff Dryer.--There are various methods for keeping buffs dry and free from dust. Some place a sheet of iron against the wall at an angle sufficient to put a lamp between it and the wall, and then let the buff rest against the top of the sheet. By this method the buff is for its full length close to the heated iron, and at the same time exposed to the heated atmosphere and any dust that may be free.
I would recommend some arrangement by which the buff would be inclosed.
I have found the following to answer the purpose well, which is a box of sheet iron twenty inches long, eight wide and five high, with one end left open and the other closed; the cover is made of the same material, with the edges bent over to go on and off.