更新时间：2020-05-22 20:04:10
封面
版权信息
内容提要
Chapter 1 INTRODUCTION
1.1 BASIC CONCEPTS AND DEFINITIONS
1.1.1 Monomers and Polymers
1.1.2 Structural Unit and Repeating Unit
1.1.3 Dimers，Trimers and Oligomers
1.1.4 Linear Polymers
1.1.5 Branched Polymers
1.1.6 Crosslinked Polymers
1.1.7 Stars and Dendrimers
1.1.8 Ladder Polymers
1.1.9 Copolymers
1.2 AVERAGE MOLECULAR WEIGHT AND DISTRIBUTION
1.3 TYPES OF POLYMERS AND POLYMERIZATIONS
1.3.1 Condensation Reactions
1.3.2 Addition Reactions
1.3.3 Ring-opening Polymerizations
1.4 POLYMERIZATION MECHANISM
1.4.1 Step Polymerization
1.4.2 Chain Polymerization
1.4.3 Comparison of Step and Chain Polymerization
1.5 NOMENCLATURE OF POLYMERS
1.5.1 Nomenclature Based on Source
1.5.2 Nomenclature Based on Structure（Non-IUPAC）
1.5.3 Trade Name
1.5.4 IUPAC Structure-Based Nomenclature System
1.6 A BRIEF HISTORY OF SYNTHETIC POLYMERS
1.6.1 1838-1930’s
1.6.2 1930-1945’s
1.6.3 1945-1960’s
1.6.4 1960-1980’s
1.6.5 1980-2000’s
1.6.6 2000-2018’s
1.6.7 Prospect of Polymer Materials
1.7 HISTORY OF NOBEL PRIZES FOR POLYMER SCIENCE
1.8 APPLICATION OF POLYMERS
Exercises 1
Chapter 2 FREE-RADICAL POLYMERIZATION
2.1 INTRODUCE
2.1.1 Initiators
2.1.2 Monomers
2.1.3 Solvents and Systems
2.2 INITIATION
2.2.1 Initiation by Thermal Decomposition of Initiators
2.2.2 Initiation by Redox Reactions
2.2.3 Initiation by Photolytic and Ionizing Radiation
2.2.4 Reactions of Initiator Radicals with Monomers
2.3 RADICAL CHAIN PROPAGATION
2.4 CHAIN TRANSFER REACTIONS
2.5 FREE RADICAL CHAIN TERMINATION
2.6 KINECTICS OF FREE RADICAL POLYMERIZATION
2.6.1 Approximations
2.6.2 Steady-state Concentrations of the Propagating Radicals
2.6.3 Theoretic Rate of Polymerization
2.7 AVERAGE KINETIC CHAIN LENGTH
2.8 AVERAGE DEGREE OF POLYMERIZATION AND AVERAGE MOLECULAR WEIGHT
2.9 EFFECT OF CHAIN TRANSFER ON AVERAGE DEGREE OF POLYMERIZATION
2.10 DEPENDENCE OF THE DEGREE OF POLYMERIZATION ON TEMPERATURE
2.11 DISTRIBUTION OF MOLECULAR WEIGHT
2.11.1 Disproportionation Termination
2.11.2 Combination Termination
2.12 INHIBITOR AND RETARDER
Exercises 2
Chapter 3 FREE-RADICAL COPOLYMERIZATION
3.1 TYPES AND NAMENCLATURE OF COPOLYMERS
3.2 REACTIVITY RATIO AND COPOLYMER COMPOSITION EQUATION
3.3 COPOLYMERIZATION BEHAVIOR
3.3.1 Ideal Copolymerization
3.3.2 Alternating Copolymerization
3.3.3 Non-ideal Copolymerization
3.3.4 "Block" Copolymerization
3.4 EXPERIMENTAL DETERMINATION OF ACTIVITY RATIOS
3.5 VARIATION OF COPOLYMER COMPOSITION WITH CONVERSION
3.6 EFFECT OF MONOMER STRUCTURE ON REACTIVITY
3.6.1 Conjugation Effect
3.6.2 Polarity Effect
3.6.3 Steric Effect
3.7 Q-e EQUATIONS
3.8 DISTRIBUTION OF MONOMERS IN A COPOLYMER
Exercises 3
Chapter 4 IONIC POLYMERIZATION
4.1 ANIONIC POLYMERIZATION
4.1.1 Initiators for Anionic Polymerization
4.1.2 Monomers for Anionic Polymerization
4.1.3 Solvents
4.1.4 The Mechanism of Anionic Polymerization（General）
4.1.5 Living Polymers and Copolymerization
4.2 COORDINATION POLYMERIZATION
4.2.1 Ziegler-Natta Catalyst
4.2.2 Composition of the Catalyst
4.2.3 Polymerization Mechanism
4.3 CATIONIC POLYMERIZATION
4.3.1 Initiators for Cationic Polymerization
4.3.2 Monomers for Cationic Polymerization
4.3.3 The Mechanism of Cationic Polymerization
4.3.4 Special Characteristics of Classical Cationic Polymerizations
4.4 KINETICS OF IONIC POLYMERIZATION
4.4.1 Anionic Polymerization
